Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 6, Pages 4430-4440Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00157
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Funding
- National Natural Science Foundation of China (NSFC) [NSFC-21673004]
- National Natural Science Foundation of China [21901142]
- Natural Science Foundation of Shandong Province [ZR2019QB001]
- Key Research and Development Program of Shandong Province [2017CXGC1401]
- Natural Science Foundation of Jiangsu Province [BK20180227]
- Fundamental Research Funds of Shandong University [21310088963023, 2020QNQT007, 2020QNQT009]
- Chinese Scholarship Council
- HaiNan Provincial Natural Science Foundation of China [20152023]
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x-membered lactams were synthesized via either an amidation of sp(3) C-H bonds or an electrophilic substitution of arenes via Ir-nitrene intermediates. With the employment of a readily available iridium catalyst in dichloromethane or hexafluoro-2-propanol, a wide range of lactams were synthesized in good to excellent yields with high selectivity.
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