Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 4, Pages 1894-1905Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02573
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Funding
- Fonds der Chemischen Industrie
- Studienstiftung des Deutschen Volkes
- Heinrich-Heine-Universitat Diisseldorf
- Forschungszentrum Julich GmbH
- University of Cologne
- DFG
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Herein we show a novel approach toward the allylation of indoles. Thereby, we explore a class of bench-stable allylboronates and fine-tune their reactivity. The allylations of different substituted indoles proceed with negligible diastereo- and excellent enantioselectivities. This surprising selectivity (up to 99:1 er, up to approximate to 60:40 dr) is rationalized by DFT calculations.
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