Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 302, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molliq.2020.112549
Keywords
Fluorescent sensor; Fluoride detection; Colorimetric and ratiometric; Logic gate; Oxyfluorfen
Funding
- Natural Science Foundation of Heilongjiang Province [LH2019B002]
- Postdoctoral Foundation of Hei Long Jiang Province [LBH-Z17014]
- Young Talent Plan of Northeast Agricultural University [17QC24]
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A dual-modal colorimetric and fluorescent probe based on 1,8-naphthalimide, 4-(2,2-dichloroacetamide)-N-nbutyl-naphthalimide (CNA), has been designed and synthesized for the detection of fluoride anion (F ) in CH3CN. CNA exhibited highly sensitivity and selectivity for F- over the other anions, such as Cl-, Br-, I-, NO3-, ClO4, HSO4-, NO2- and SCN-. The evident colorless to yellow color change of the solution of CNA was observed with the naked eyes only in the presence of F- among the other anions, together with drastically fluorescence quenched. The Job's plot analysis revealed that the binding between the CNA with r was in 1:1 stoichiometry. The detection limits of the CNA for F- from fluorescence and ratiometric absorption spectra were 0.52, 1.41 mu M, respectively. The H-1 NMR titration indicated that F- induced the deprotonation of the CNA through hydrogen bonding interaction between amino group of the CNA and F-. Based on this detection system, an IMPLICATION logic gate could be constructed. Furthermore, it could be successfully employed as a selective fluoride anion probe to the fluorescence detection of fluorine containing pesticides (oxyfluorfen). (C) 2020 Elsevier B.V. All rights reserved.
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