Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 30, Issue 7, Pages 2489-2498Publisher
SPRINGER
DOI: 10.1007/s10904-020-01479-9
Keywords
Hydroxyapatite; Tricalcium phosphate; Montmorillonite; Triphasic ceramics; Biocomposites
Categories
Ask authors/readers for more resources
In recent years, the development of calcium phosphate/clay composites for bone tissue engineering attracted a lot of interest. In this study, novel bio-composites composed of hydroxyapatite (HAP), alpha and beta-tricalcium phosphate (alpha, beta-TCP) and sodium-montmorillonite (MNa) were developed. The composites were prepared by sintering at 900 degrees C of calcium-apatite powders in the presence of various amounts of MNa. The calcium-apatite precursors were prepared by the wet precipitation method with two desired Ca/P molar ratios (1.660 and 1.623). Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were used to characterize the prepared composites. The results showed that during the sintering process, a surface interaction apatite/MNa led to the incorporation of clay ions into the apatite structure resulting in its decomposition and formation of composite ceramics comprising HAP, beta and alpha-TCP. The decomposition of apatite increased with increasing MNa content and with decreasing Ca/P ratio. The decomposition of stoichiometric HAP led to triphasic ceramics with substituted-HAP as the major phase while the decomposition of calcium-deficient HAP led to triphasic ceramics with substituted-alpha-TCP as the major phase. Combination of MNa-clay phase and substituted-alpha-TCP can improve both mechanical and biological properties of the prepared composites.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available