Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 385, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2019.121517
Keywords
PET; Microplastics; Microfiber; Marine litter; HPLC
Categories
Funding
- University of Pisa, Italy
- PRA program [PRA2017_17]
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Microplastics are ubiquitous pollutants in marine and freshwater bodies. Poly(ethylene terephthalate) microfibers (PMFs) are among the main printery microplastics (as-produced polymer microparticles). Released in large amounts in laundry wastewaters, PMFs end up in freshwater and marine sediments due to their high density. PMFs are potentially hazardous pollutants for ecosystems and human health, being a deceiving food source for animal organisms at the base of the food chain (e.g. sediment and water filtrators, including edible shellfish and small crustaceans). This study describes a simple, sensitive and versatile procedure for quantifying the total mass of PET micro- and nano-particles in sediments. The procedure involves aqueous alkaline PET depolymerization with phase transfer catalysis, oxidation and fractionations to remove interfering species and pre-concentrate the terephthalic acid (WA) monomer, and WA quantification by reversed-phase HPLC. Recovery of TPA from a model sediment spiked with 800 ppm PET micropowder was 98.2 %, with limits of detection/quantification LOD = 17.2 mu g/kg and LOQ = 57.0 mu g/kg. Analyses of sandy sediments from a marine beach in Tuscany, Italy, showed contamination in the 370-460 mu g/kg range, suggesting that a not negligible fraction of PET microfibers released in surface waters ends up in shore sediments.
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