Synergetic effects of defects and acid sites of 2D-ZnO photocatalysts on the photocatalytic performance

Regulation of defects and surface acidic sites of photocatalysts is an efficient approach to improve the photocatalytic activity. Ultrathin 2D-ZnO photocatalysts were prepared to uncover the synergetic effects of defects and surface acidic sites on the photocatalytic activity. The reaction constant for photocatalytic degradation of MB upon ZnO-S is 2.26, 2.82, 12.2 times higher than that of SH-500, SO-500, and ZnO-R, respectively. The results revealed that the surface defects, hydroxyl group and chemisorbed water played pivotal roles in the generation of reactive oxygen species (ROS). Although the limited improvement of visible absorption was achieved after introduction of oxygen vacancy (V-o), the overall photocatalytic activity decreased due to the reduced ROS production capacity shown by density functional theory (DFT) calculations. Hydroxyl radical is the key ROS in degradation of organics, and electron contributes a little bigger than hole in the generation of hydroxyl radical. Importantly, the decrease in surface acidic sites resulted in the decreased photocatalytic activity, proven by the dynamics of photoinduced carriers. This study reveals that the improved photocatalytic activity of 2D-ZnO photocatalysts can be attributed to the synergetic effects of surface defects and acidic sites rather than the enhanced visible absorption resulted from the V-o introduction.