Journal
JOURNAL OF CATALYSIS
Volume 382, Issue -, Pages 237-246Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2019.12.019
Keywords
Self pressurizing cell; Hydrogen; Electrochemical reforming; Ethanol; PdCoP
Categories
Funding
- Ente Cassa di Risparmio di Firenze
- PRIN 2017 Project - Italian Ministry MUIR Italy [2017YH9MRK]
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The electrochemical reforming of ethanol to H-2 is achieved at 150 degrees C in an autoclave electrochemical cell that allows the safe pressurization of the H-2 produced as no O-2 is evolved. The alkaline conditions are very aggressive to catalysts including noble metals like Pt and Pd. We report a highly active ethanol oxidation catalyst (PdCoNifoam) composed of Pd nanoparticles supported on nanostructured Co oxide structures grown on nickel foam. Treatment with phosphorous vapors at high temperature yields a thin coating of phosphate that confers enhanced stability to the electrode operating in an electrolysis cell at 150 degrees C. A combination of scanning electron microscopy (energy dispersive X-ray spectroscopy) and X-ray photoelectron spectroscopy reveal a 3D nano-flake surface with an external layer of phosphates that prevents Pd dissolution. The PdCoP@Ni-foam catalyst was successfully used for ethanol electrochemical reforming at 150 degrees C with self-pressurization of the H-2 produced by the electrochemical reaction. (C) 2019 Elsevier Inc. All rights reserved.
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