Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 815, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.152276
Keywords
CoFe-LDH; CeO2; Peroxidase-like activity; Hierarchical-porous; Colorimetric sensing; Glucose
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Funding
- National Natural Science Foundation of China [51672110, 51172095]
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Biomass-derived hierarchically porous CoFe-LDH (layered double hydroxides)/CeO2 hybrid possessing an inherent peroxidase-like activity was first fabricated employing kapok as bio-template. The CeO2 fibers not only exhibited peroxidase-like activity, but also served as a support and guided the deposition of CoFe-LDH nanosheets on their surface to form a hierarchically porous network. The resultant CoFe-LDH/CeO2 hybrid acted as a peroxidase mimic to catalyze 3,3',5,5'- tetramethylbenzidine (TMB) with H2O2 to generate a typical blue colored product. Furthermore, CoFe-LDH/CeO2 hybrid displayed superior peroxidase-like catalytic property compared to the pristineCeO(2) and CoFe-LDH, which was attributed to the presence of more effective active sites of unique hierarchical-porous architecture and the synergistic effect between CoFe-LDH and CeO2. A facile and sensitive sensing system for H2O2 and glucose determination was successfully proposed, which exhibited a sensitive response to glucose ranging from 0.05 -2 mM with a detection limit of 0.015 mM based on the accelerated electron transfer between TMB and H2O2 with the assistance of CoFe-LDH/CeO2. This paper offered a feasible way or the fabrication of materials with hierarchical structure and provided a new insight into seeking novel peroxidase mimics with boosted catalytic activities. (C) 2019 Elsevier B.V. All rights reserved.
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