Journal
ISRAEL JOURNAL OF CHEMISTRY
Volume 60, Issue 3-4, Pages 281-293Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201900166
Keywords
photoredox catalysis; radical polar crossover; catalysis; redox-neutral; radical
Categories
Funding
- NIGMS [R01 GM 113878, R01 GM 111465, R35 GM 131680]
- NSF
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Radical/Polar Crossover (RPC) chemistry is a rapidly growing subset of photoredox catalysis that is characterized by transformations featuring both radical and ionic modes of reactivity. Net-neutral RPC is particularly interesting in that both the single-electron oxidation and reduction steps occur through interaction with the photocatalyst, thus precluding the need for exogenous oxidants or reductants. As such, these transformations facilitate rapid incorporation of molecular complexity while maintaining mild reaction conditions. This review covers recent advances in photoredox-mediated net-neutral RPC synthetic methods, with a particular emphasis on C-C bond-forming reactions.
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