Journal
ISRAEL JOURNAL OF CHEMISTRY
Volume 60, Issue 3-4, Pages 351-359Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201900177
Keywords
decarboxylative; allylation; palladium; photoredox
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Funding
- National Science Foundation [CHE-1800147]
- Kansas Bioscience Authority Rising Star program
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Since early focus on development of the allylation of non-stabilized enolates, decarboxylative allylation has undergone tremendous evolution. This account describes the progression of decarboxylative allylation within the Tunge group with a focus on efforts to identify and overcome pK(a) requirements that initially limited the carboxylates that would undergo decarboxylative allylation.
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