Journal
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
Volume 17, Issue 3, Pages 1479-1489Publisher
WILEY
DOI: 10.1111/ijac.13467
Keywords
CuO; electrospinning; photocatalysis; p-n heterojunctions; SnO2
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In this study, CuO-SnO2 p-n type heterostructures were produced and tested for the degradation of methylene blue and 4-nitrophenol under visible light irradiation. CuO particles were produced in plate-like morphology using hydrothermal synthesis. SnO2 nanofibers were obtained by electrospinning. Structural, morphological, optical and semiconducting property characterization of heterostructured CuO-SnO2 and individual phases were performed. The photocatalytic activity was found to change depending on the amount of CuO particles in heterostructured samples. Among others, the sample with 0.35 wt.% CuO-SnO2 showed the highest photocatalytic efficiency with a degradation rate constant 2 h(-1). Active specie scavenger tests revealed that the decomposition reaction occurs through direct oxidation mechanism by the holes in the valence band of SnO2 in pure samples whereas in CuO-SnO2 samples center dot O2- and center dot OH radicals also form and involve in the reactions. Further, the photocatalytic degradation mechanism was revealed using relative band potentials and p-n junctions of the heterostructured photocatalyst.
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