4.7 Article

Is It Possible To Prepare a Heterometal Anderson-Evans Type Anion?

Journal

INORGANIC CHEMISTRY
Volume 59, Issue 4, Pages 2116-2120

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02898

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Funding

  1. Russian Science Foundation [RSF 19-73-10027]
  2. Ministry of Science and Higher Education of the RF
  3. Russian Science Foundation [19-73-10027] Funding Source: Russian Science Foundation

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Reaction of [SbW9O33](9-) with [Pt(H2O)(2)(OH)(4)] results in the first example of the mixed addenda Anderson-Evans type Pt-IV{Sb-V(OH)(2)}(W5O22)-O-VI](7-) anion, isolated and characterized as K6Na2[Pt{Sb(OH)(2)}W5O22](NO3)(0.1)(OH)(0.9)center dot 11H(2)O (1).

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