Journal
INORGANIC CHEMISTRY
Volume 59, Issue 2, Pages 1323-1331Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03032
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Funding
- National Natural Science Foundation of China [21801187]
- Science & Technology Development Fund of Tianjin Education Commission for Higher Education [2017KJ127]
- Foundation of Development Program of Future Expert in Tianjin Normal University [WLQR201812]
- Doctoral Program Foundation of Tianjin Normal University [043135202-XB1702]
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We first design and synthesize a dendritic aromatic 6-carboxyl linker (H6TDCPB), which is successfully assembled with Cd(II) ion to construct a porous metal-organic framework with a raw Cd-6 cluster, {[Cd-3(TDCPB)center dot 2DMAc]center dot DMAc center dot 4H(2)O}(n) (namely, complex 1). More interestingly, six adjacent linkers are packed together by pi-pi-stacking interactions to form an amazing six-molecule accumulation in the crystal structure. By virtue of high stability and luminescent properties, the as-synthesized sample not merely owns an excellent detectable ability but also possesses an outstanding selectivity for nitrofurans with remarkable recursitivity.
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