Journal
INORGANIC CHEMISTRY
Volume 59, Issue 6, Pages 3874-3886Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03549
Keywords
-
Categories
Funding
- Nanyang Technological University [M4080454, 2017-T1-001-175-02]
Ask authors/readers for more resources
A synthetic procedure for obtaining a chiral P,N ligand was developed by exploiting the versatility of the asymmetric hydrophosphination protocol catalyzed by a phosphapalladacycle complex. The addition of the synthesized ligand to various metal sources led to the generation of chiral and enantioenriched chelate complexes, which can be useful prototypes for catalyst design in the future. The resulting coordination compounds were comprehensively characterized by solid-state (Xray crystallography) and solution-based (one- and two-dimensional NMR spectroscopy) techniques and natural bond orbital (density functional theory) analysis to determine their structural and key electronic features.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available