4.7 Article

Minimum ignition temperature of carbonaceous dust clouds in air with CH4/H2/CO below the gas lower explosion limit

Journal

FUEL
Volume 264, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2019.116811

Keywords

Ignition temperature; Carbonaceous dust; Flammable gas; Ignition mechanism; Concentration effect; Volatile content

Funding

  1. National Key R&D Program of China [2017YFC0804700]
  2. Fundamental Research Funds for the Central Universities [2019SCUH0004]
  3. China Postdoctoral Science Foundation [2018M640918]
  4. opening project of State Key Laboratory of Explosion Science and Technology [KFJJ19-14M]
  5. Beijing Institute of Technology

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Godbert-Greenwald furnace was used to investigate the minimum ignition temperature of dust clouds (MITC) in air with the presence of flammable gas which is lower than its lower explosion limit (LEL). Three flammable gases (CH4, H-2 and CO) and three carbonaceous dusts (anthracite coal, bituminous coal and sweet potato starch) were tested. Results showed that all flammable gases have distinct effects on the MITC of the dust samples and volatile matter content of dust plays an important role during the ignition process. Specifically, the MITC of anthracite coal dust decreased from 610 degrees C to 560 degrees C, 580 degrees C and 570 degrees C with 3% CH4, 3% CO and 2.5% H-2, respectively. Moreover, a heterogeneous ignition mechanism model was proposed to verify the equally global ignition characteristic between hybrid anthracite coal-CxHy mixture and bituminous coal. All three gases had an ignorable effect on the MITC of starch dust considering the experimental error. The presence of CO and H-2 slightly promoted the ignition of bituminous coal dust, but the addition of CH4 showed a distinct concentration effect on the MITC of bituminous coal: the MITC decreased with 1% CH4 while increased with 2% and 3% CH4. This negative-effect of flammable gases at such low concentrations on ignition temperature of bituminous coal dusts was found for the first time. Furthermore, the presence of the 2nd flammable gas had a smaller effect on the MITC of dust samples with a higher volatile content, resulted from the competition of heterogeneous and homogeneous ignition mechanisms.

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