Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2020, Issue 19, Pages 2842-2845Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000062
Keywords
Ruthenium; Alkenylation; Acylgermane; Styrene; C-H bond activation
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In this communication, a ruthenium-catalyzed ortho-alkenylation of acylgermanes with electron-deficient alkenes through direct C-H bond activation has been developed. With acylgermane as the directing group, this method provides a straightforward access to diverse acylgermanes derivatives with good functional group tolerance and site-selectivity under mild reaction conditions.
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