Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2020, Issue 4, Pages 506-509Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901793
Keywords
Fluorine; Indoles; Photoredox catalysis; Selenium; Trifluoromethylselenation
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Funding
- LabEx Charmmmat
- Agence Nationale de la Recherche (ANR) [ANR 18-CE07-0039-01]
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A metal-free visible-light-promoted regioselective trifluoromethylselenolation of electron-rich heteroarenes has been developed using C-H functionalization. This eco-friendly, atom-economical, and easy-to-operate protocol provides direct access to a wide range of functionalized SeCF3-containing heteroarenes in high yields, and is amenable to continuous flow techniques. A radical mechanism was supported by EPR experiments.
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