One-pot synthesis of Cr(III)-incorporated Zr(IV) oxide for fluoride remediation: a lab to field performance evaluation study

A low-cost Cr(III)-incorporated Zr(IV) bimetallic oxide (CZ) was synthesized by simple chemical precipitation method for removal of fluoride from contaminated water. The physicochemical properties of CZ before and after fluoride removal were established with several instrumental techniques such as TEM with elemental mapping, SEM with EDX, XRD, IR, XPS, zeta potential measurement, etc. Batch adsorption technique were carried out to understand the factors affecting fluoride adsorption, such as effects of initial pH, adsorbent dose, co-occurring ions, contact time, and temperature. The maximum adsorption capacity observed at pH between 5 and 7. The fluoride adsorption processes on CZ obeyed the pseudo-second-order rate equations and both Freundlich and DR isotherm models. The maximum adsorption capacity of 90.67 mg g(-1) was obtained. The thermodynamic parameters Delta H-0 (positive), Delta S-0 (positive), and Delta G(0) (negative) indicating the fluoride sorption system was endothermic, spontaneous, and feasible. The CZ also successfully used as fluoride adsorbent for real field contaminated water collected from the Machatora district, Bankura, West Bengal, India.