Journal
ELECTROCHIMICA ACTA
Volume 332, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.135490
Keywords
MoS2; Yolk shell morphology; Lithium-ion batteries; DFT; N/P doping
Categories
Funding
- National Natural Science Foundation of China [51803062]
- Natural Science Foundation of Zhejiang Province [LY17E030006, LY18E030009, LY19E030007]
- Xin Miao Talent Program of Zhejiang Province [2018R403052]
- Natural Science Foundation of Guangdong Province [2018A030310379, 2019A1515012125]
- Science and Technology Program of Guangzhou [201904010272]
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A facile route for the N/P doped Mo(S)2@ poly (cyclotriphosphazene-co-4,4-sulfonyldiphenol)-C (MoS2@PZS-C) yolk shell nanostructure has been presented. The obtained MoS2@PZS-C nanospheres has a unique advantage of yolk shell morphology, due to the internal void space (floc porous structure formed by oligomers) with a high surface area (573.9 m(2) g(-1)), which can not only provide enough reaction sites to store electrical charge, but also accelerate the reaching of reaction sites by ions flux permeation. Even if the volume expansion causes the structure to be destroyed, the pulverized active material is still wrapped in the conductive material to achieve stable electrical contact. Using the MoS2@PZS-C nanospheres as anode material in lithium-ion batteries (LIBs), it presented enhanced cycle stability with high specific capacity (1245 mA h.g(-1)) and good rate capability. At the same time, DFT calculations showed that N, P, S doped modified carbon structure can improve the binding energy of materials and lithium ion/atoms, and change the local charge density of materials to produce more active sites. What's more, the defects caused by doping can increase the electron chemical activity and electron transport rate of the material. It reveals the cause of the PZS-C electrode with high electrochemical performance. (C) 2019 Elsevier Ltd. All rights reserved.
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