Journal
ELECTROCHIMICA ACTA
Volume 337, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.135772
Keywords
Lithium-sulfur battery; Sulfur cathode; Cycling stability; Ruthenium dioxide; Tap density
Categories
Funding
- National Natural Science Foundation [21935006, 21421001]
- Fundamental Research Funds for the Central Universities of China
Ask authors/readers for more resources
Lithium-sulfur battery is recognized as one of the most promising next-generation energy storage devices. However, the low specific capacity and inferior cycling stability of cathode are real bottlenecks in practical lithium-sulfur battery, owing to the low sulfur content and tap density of cathode with lightweight and nonpolar carbon host materials. In this study, conductive RuO2 stacking microspheres are designed and demonstrated as sulfur immobilizer for lithium-sulfur battery. The stacked RuO2 microspheres exhibit not only good conductive framework for both the transport of electrons and diffusion of electrolyte, but outstanding electrocatalytic activity for the conversion of lithium polysulfides. Moreover, the polarity of RuO2 is helpful to trap and confine soluble polysulfides during cycling. With a high tap density of 1.4 g cm(-3) and high sulfur content of 81.8 wt%, the S/RuO2 composite delivers a high gravimetric and volumetric capacity of 985 mAh g(-composite )(-1)and 1360 mAh cm(-composite )(-3)at 0.2 C rate, respectively. Resulting from the fast redox kinetics, an excellent rate capability of 479 mAh g(-composite)(-1) can be also obtained at 5 C rate. Overall, this work unfolds a potential strategy to realize the combination of high energy density and improved cycling stability of lithium-sulfur battery. (C) 2020 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available