Shuttle-like CeO2/g-C3N4 composite combined with persulfate for the enhanced photocatalytic degradation of norfloxacin under visible light

In this work, the shuttle-like CeO2 modified g-C3N4 composite was synthesized and was combined with persulfate (PS) for the efficient photocatalytic degradation of norfloxacin (NOR) under visible light. Scanning and transmission electron microscopy (SEM and TEM), X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) emission spectra were used to characterize the structural and optical properties of the as-prepared catalysts. Active species trapping experiments demonstrated that additional sulfate radicals (center dot SO4-) formed upon the addition of PS which could cooperate with superoxide radicals (center dot O-2(-)), holes (h(+)) and hydroxyl radicals (center dot OH) to decompose NOR. Singlet oxygen (O-1(2)) was also formed during the reaction and acted as an important active species. The degradation products of NOR were also identified and analyzed by using LC-MS technology, and the possible degradation mechanism and pathways were proposed and discussed. This work indicated that the shuttle-like CeO2 modified g-C3N4 coupled with PS displayed promising applications in the field of pharmaceutical wastewater purification.