Journal
DESALINATION
Volume 473, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.desal.2019.114169
Keywords
Reverse osmosis; Interfacial polymerization; Surface modification; Zwitterion; Antifouling performance
Categories
Funding
- National Natural Science Foundation of China [51708408]
- ChangJiang Scholars and Innovative Research Team in the University of Ministry of Education, China [IRT-17R80]
- Program for Innovative Research Team in University of Tianjin [TD13-5044]
- Science and Technology Plans of Tianjin [17PTSYJC00060, 18JCZDJC37100]
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It is well known that the water flux and antifouling performance of polyamide (PA) membrane are strongly associated with their surface characters, especially for surface hydrophilicity, roughness, and charge. In this study, a zwitterionic surface TFC reverse osmosis (RO) membrane was fabricated by small molecule 3-bromo-propionic (3-BPA) modification on the pristine membrane that fabricated through interfacial polymerization (IP) technique using a new aqueous monomer 4-morpholinobenzene-1,3-diamine (MpMPD) and trimesoyl chloride (TMC). The as-fabricated RO membranes were well analyzed by various techniques, that the zwitterionic MpMPD-PA membrane surface exhibited greatly enhanced hydrophilicity with water contact angle of 28.1 degrees and surface roughness as low as 26.0 nm. The water permeability of membrane MpMPD-PA reached 1.65 L m(-2) h(-1) bar(-1), which exhibited similar to 24% increase compared to our lab-made MPD membrane, meanwhile kept a high NaCl rejection of 97.8%. In addition, the dynamic fouling experiments illustrated that the zwitterionic surface RO membrane possess excellent fouling resistance to protein BSA, polysaccharides SA, and surfactant SDS. Therefore, this work provide a simple and convenient way to fabricate novel zwitterionic surface RO membrane with high performance from the molecular level design.
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