Journal
CURRENT ORGANIC CHEMISTRY
Volume 23, Issue 19, Pages 2005-2015Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272823666191021120336
Keywords
beta-Keto amides; diketene; beta-keto acids; Meldrum's acid; enamines; enolates; Passerini products
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This review summarizes the data published on the methods of preparation of beta-keto amides as a versatile synthon for many heterocyclic rings and asymmetric urea derivatives. Based on the starting materials used for the synthesis of beta-keto amides, eight methods were reported including beta-keto acids and their derivatives, Meldrum's acid and their derivatives, diketene, 2,6-dimethyl-1,3-dioxin-4-one derivatives (TMD), alpha-diazo ketones, enamines and etiolates, acetamides and their derivatives and reduction of certain Passerini products.
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