Journal
COORDINATION CHEMISTRY REVIEWS
Volume 402, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2019.213066
Keywords
Calixarenes; Magnetism; Supramolecular chemistry; Cluster compounds
Categories
Funding
- ARC [DE180100112]
- Australian Research Council [DE180100112] Funding Source: Australian Research Council
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Multinuclear metal complexes have shown a unique capacity to provide interesting magnetic, chemical and electronic properties by virtue of the remarkably diverse range of structural types that they exhibit. Calix[n]arenes are now a mature synthetic platfom that provide for a diverse spatial arrangement of binding groups, making them highly suitable to use for the formation of multinuclear metal ion complexes. Increasing interest has been shown in the development and properties of magnetic materials based on calixarene macrocycles. Here, we review the magnetic properties of calixarene-supported metal clusters with emphasis on those examples exhibiting slow magnetic relaxation. (C) 2019 Elsevier B.V. All rights reserved.
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