4.7 Article

Assessment on the performances of air lime-ceramic mortars with nano-Ca(OH)2 and nano-SiO2 additions

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 232, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2019.117163

Keywords

Ca(OH)(2); SiO2; Nanoparticles; Lime mortars; Roman ceramic; Pozzolanic activity; Carbonation

Funding

  1. project CLIMORTEC of Ministry of Economy and Competitiveness of Spain [BIA2014-53911-R]
  2. project TOP Heritage of the Community of Madrid [P2018/NMT-4372]
  3. Moncloa Campus of International Excellence (UCM-UPM) [CEI-09-009]
  4. group of Petrology applied to the Heritage Conservation [921349]

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This research presents a novel approach based on the combination of nanotechnology and Roman technology by investigating how adding nanoCa(OH)(2) and nanoSiO(2) modify the performance of air lime mortars containing Roman ceramics. Microstructural, physico-mechanical properties were periodically controlled until 120 days of curing. XRD and TGA analyses showed that adding nanoSiO(2) either alone or with nanoCa(OH)(2) were more beneficial to improve the pozzolanic activity in the mortars. The less stable hydrated phases generated led to microcracks which eventually impaired compressive strength but enhanced deformability capacity. These results provide insight into the development of highly compatible mortars for cultural heritage. (C) 2019 Elsevier Ltd. All rights reserved.

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