4.5 Review

Recent Advances and Perspectives in Transition Metal-Catalyzed 1,4-Functionalizations of Unactivated 1,3-Enynes for the Synthesis of Allenes

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 38, Issue 1, Pages 91-100

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201900277

Keywords

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Funding

  1. National Basic Research Program of China [973-2015CB856600]
  2. National Natural Science Foundation of China [21532009, 21761142010, 21790330, 21821002]
  3. Science and Technology Commission of Shanghai Municipality [17XD1404500, 17QA1405200, 17JC1401200]
  4. Chinese Academy of Sciences [QYZDJSSWSLH055, XDB20000000]

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Classic methods for the synthesis of allenes usually introduce only one functional group into products. In this review, we highlight the recent advances and perspectives in the synthesis of allenes by transition metal-catalyzed 1,4-functionalization of unactivated 1,3-enynes.

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