Journal
CHINESE CHEMICAL LETTERS
Volume 31, Issue 7, Pages 1773-1781Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.12.015
Keywords
MOFs; Photoelectrocatalysis; Photoelectrode; CO2 conversion; Water splitting
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Funding
- Natural Science Foundation of Jiangsu Province of China [BK20160430, BK20181070]
- National Natural Science Foundation of China [51808250]
- China Postdoctoral Science Foundation [2016M591757, 2017M610336]
- Jiangsu Planned Projects for Postdoctoral Research Funds of China [1601179C]
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Semiconductor-based photoelectrocatalytic processes have attracted considerable research interest for solar energy collection and storage. Photoelectrocatalysis is a heterogeneous photocatalytic process in which a bias potential is applied to a photoelectrode, and thus the photoelectrocatalytic performance is closely related to the photoelectrode prepared by semiconductors. Among various semiconductors, metal-organic frameworks (MOFs) have attracted more and more attention because of their unique properties such as optical properties and adjustable structure. Herein, a comprehensive review on different MOFs (Ti-based, Zn-based, Co-based, Fe-based, Cu-based, and mixed metal-based MOFs) for heterogeneous photoelectrocatalysis is carried out and, in particular, the application of this technique for CO2 conversion and water splitting is discussed. In addition, the challenges and development prospects of MOFs in photoelectrocatalysis are also presented. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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