Novel cyclodextrin-based adsorbents for removing pollutants from wastewater: A critical review

Over the past few decades, cyclodextrin-based adsorbents have drawn worldwide attention as new-generation adsorbents for wastewater treatment due to its extraordinary physicochemical properties. This review outlined the recent development in the synthesis of cyclodextrin-based adsorbents as well as highlighted their applications in the removal of heavy metals, dyes, endocrine disrupting chemicals (EDC5), and mixed pollutants from water. The cross-linked and immobilized cyclodextrin-based adsorbents exhibited excellent adsorption performances. The removal of dyes and heavy metals were effectively controlled by ion exchanging, mainly depending upon the pH; while the adsorptions of EDC5 always occurred in cyclodextrin cavities and pH-independent. An easier separation process between aqueous and adsorbents could be achieved compared to native cyclodextrin, which promoted the application of cyclodextrin-based adsorbents in practical industry. This review could provide an inspiration for the advanced study in the development of cyclodextrin-based adsorbents for high efficiency wastewater treatment. (C) 2019 Elsevier Ltd. All rights reserved.