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N-Centered Radical Directed Remote C-H Bond Functionalization via Hydrogen Atom Transfer

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 15, Issue 6, Pages 651-672

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201901744

Keywords

N-centered radical; hydrogen atom transfer; remote functionalization; C-N; C-C bond formation; heterocycles

Funding

  1. Indian Institute of Technology, Ropar
  2. SERB, DST, India [ECR/2018/000098]
  3. IIT Ropar

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The N-centered radical directed remote C-H bond functionalization via hydrogen-atom-transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C-H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days ' developments in this field of unactivated remote C-H bonds functionalizations.

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