Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 15, Pages 3259-3263Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000154
Keywords
charge transfer; iron-cobalt; photo-switchable; slow magnetic relaxation
Categories
Funding
- China Scholarship Council
- MEXT KAKENHI [17H01197, 17K19140]
- Grants-in-Aid for Scientific Research [17K19140, 17H01197] Funding Source: KAKEN
Ask authors/readers for more resources
Some cyanide-bridged complexes are known for exhibiting slow magnetic relaxation behavior in a light-induced metastable state. Herein, an unexpected reverse effect is observed for the first time in the S=1/2 {Fe-LS(II)-Co-LS(III)-Fe-LS(III)} (HS=high spin, LS=low spin) ground state of a novel V-shaped trinuclear cyanide-bridged {Fe2Co} complex. In this complex, light-switchable iron-cobalt charge transfer with repeatable off/on switching of slow magnetic relaxation is discovered upon alternating laser irradiation at 785 and 560 nm. An important characteristic of the present compound is that the S=1/2 ground state exhibits slow magnetic relaxation before irradiation, whereas this is accelerated after irradiation. This is different from the typical behavior, where the light-induced metastable state exhibits slow magnetic relaxation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available