Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 14, Pages 3113-3118Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904590
Keywords
electron-rich systems; hot exciton; photophysics; thermally activated delayed fluorescence; twistacenes
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Funding
- National Natural Science Foundation of China [21442010, 21672051, 11704024]
- Natural Science Foundation of Hebei Province for Distinguished Young Scholars [B2017201072]
- talent training project of Hebei Province [A201902006]
- Advanced Talents Incubation Program of the Hebei University [521000981133]
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A series of twistacene-functionalized donor (D)-pi-acceptor (A) derivatives (2-5) have been designed and synthesized, in which twistacene can be regarded as a promising platform for electron-rich systems for fluorescence emitters. The connecting modes and various acceptors are also examined to investigate the effect of structural changes on the photophysical, electrochemical, and thermal properties. The strong electron-withdrawing capability of the arylboron-modified benzonitrile unit can effectively separate the HOMO and LUMO energy levels of 4/5, which is beneficial for the formation of thermally activated delayed fluorescence (TADF) molecules. Cyan and orange organic light-emitting diodes based on 4 and 5 exhibit promising electroluminescence with a maximum brightness of 7643 cd m(-2) for device-4 and 14871 cd m(-2) for device-5.
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