Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 14, Pages 3129-3136Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904948
Keywords
dynamic libraries; electrochemistry; metathesis; mixed disulfides; sulfur
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A novel approach of electrolysis using alternating current was applied in the sulfur-sulfur bond metathesis of symmetrical disulfides towards unsymmetrical disulfides. As initially expected, a statistical distribution in disulfides was obtained. Furthermore, the influence of electrode polarisation by alternating current was investigated on a two-disulfide matrix. The highly dynamic nature of this chemistry resulted in the creation of dynamic disulfide libraries by expansion of the matrices, consisting of up to six symmetrical disulfides. In addition, mixing of matrices and stepwise expanding of a matrix by using alternating current electrolysis were realised.
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