Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 10, Pages 2138-2142Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904502
Keywords
amination; amines; ethylene; hydroaminoalkylation; titanium
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Funding
- Research Training Group Chemical Bond Activation [GRK 2226]
- Deutsche Forschungsgemeinschaft
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The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti-C bond of a titanaaziridine is reported.
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