Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 27, Pages 5951-5955Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000276
Keywords
alkenes; C-F activation; fluorine; N-heterocyclic olefins; nucleophilic substitution
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Funding
- Tata Institute of Fundamental Research (TIFR) Hyderabad, Gopanpally, Hyderabad, Telangana, India from the Department of Atomic Energy (DAE), Government of India, India
- Department of Science and Technology, New Delhi, India
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [387284271-SFB 1349]
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A N-heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C-F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl-substituted alkenes in which the central carbon-carbon double bond is in a twisted geometry.
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