Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 26, Pages 5774-5779Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000253
Keywords
cyclopentadienyl ligand; hydrogen bond; ortho-bromination; phenyl carbamates; rhodium
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Funding
- JSPS (Japan) [JP26102004, 17K14481]
- Grants-in-Aid for Scientific Research [17K14481] Funding Source: KAKEN
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It has been established that a newly developed cyclopentadienyl rhodium(III) [(CpRhIII)-Rh-A] complex, bearing an acidic secondary amide moiety on the Cp ring, is able to catalyze the ortho-bromination of O-phenyl carbamates with N-bromosuccinimide (NBS) at room temperature. The presence of the acidic secondary amide moiety on the Cp-A ligand accelerates the bromination by the hydrogen bond between the acidic NH group of the Cp-A ligand and the carbonyl group of NBS.
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