Journal
CHEMISTRY OF NATURAL COMPOUNDS
Volume 56, Issue 1, Pages -Publisher
SPRINGER
DOI: 10.1007/s10600-020-02939-x
Keywords
cresols; polyprenols; alkylation; polymerization; monoalkyl product; dialkyl product
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Funding
- Basic Research Foundation of CCST RUz [FA-F7-T207]
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Alkylation by polyprenols of o- and p-cresols in the presence of equimolar amounts of the corresponding aluminum cresolates occurred regioselectively to form o-alkyl products regardless of the ratio of starting reagents. Production of 2,6-dipolyprenyl-4-methylphenol was favored if an excess of polyprenols was used with aluminum p-cresolate. A significant amount of polyprenol polymerization products was obtained under the studied reaction conditions.
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