Hydrogen Bond Formation of Bronsted Acid Sites in Zeolites

Bronsted acid sites (BAS) in dry aluminosilicate zcolites, also known as bridging O-H-H groups, may form hydrogen bonds with other framework oxygen atoms, O, in addition to BAS that are free of such interactions. These are referred to as perturbed and unperturbed BAS, respectively. However, hydrogen bonding may occur only for specific geometric orientations between two framework oxygen atoms, allowing an O-H-H center dot center dot center dot O interaction. To evaluate the possibility for such hydrogen bonding, we introduce an alignment angle kappa that describes the angle between the Si-O-H-Al bisector and the O-H-O direction of a potential hydrogen-bonding donor-acceptor pair. A total of 27 zeolite framework topologies were analyzed, and the relevance of this approach was subsequently demonstrated for H-ZSM-5 with two different Si/Al ratios. Here, it could be unequivocally shown by advanced solid-state NMR methods that the debated H-1 NMR signal at similar to 6 ppm arises due to the formation of hydrogen-bonded BAS.