Journal
CHEMISTRY OF MATERIALS
Volume 32, Issue 7, Pages 3229-3234Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.0c00375
Keywords
-
Funding
- Queensland University of Technology (QUT)
- Australian Government
- University of Queensland
- Australian Research Council (ARC) [LE170100144, DP130103157, FT140100986, FT140100273]
- EPSRC [EP/K033646/1] Funding Source: UKRI
- Australian Research Council [LE170100144, FT140100986] Funding Source: Australian Research Council
Ask authors/readers for more resources
Encasing the classic spin-crossover (SCO) complex cation [Co(terpy)(2)](2+) in different anionic supramolecular frameworks modulates its SCO behavior, tuning both its T-1/2 (shift of up to 200 K) and the cooperativity of the system. The SCO behavior is influenced by the organization of the complex cations within supramolecular anionic frameworks comprising iodoperfluoroben-zenes and iodide anions, with tighter packing of complexes leading to a more abrupt transition. This approach for the control of magnetic properties is applicable to any complex with suitable counterions and hence provides significant opportunity for further developing the properties of many such stimuli-responsive complexes, without requiring changes to their chemical structures. The magnetic properties of the materials presented herein are investigated through variable-temperature magnetic susceptibility measurements and -pressure molecular variable-temperature structure studies.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available