Journal
CHEMISTRY OF MATERIALS
Volume 32, Issue 2, Pages 882-888Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.9b04739
Keywords
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Funding
- National Natural Science Foundation of China [51702057, 11604002]
- National Science Foundation [DMR 18-47701, CER 19-11311]
- University of Houston Division of Research
- NSF [15-31814]
- U.S. Department of Energy (DOE) Office of Science, Argonne National Laboratory [DE-AC02-06CH11357]
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The photoluminescence spectrum generated by an ordinary phosphor-converted white light-emitting diode (pc-wLED) that combines a blue LED chip with a yellow phosphor or a near-UV LED with red, green, and blue phosphors contains a notable cavity in the cyan region of the visible spectrum (480-520 nm), which reduces the color quality produced by these lights. Here, we report a new bright blue-cyan-emitting phosphor, NaMgBO3:Ce3+, which bridges the gap. Rietveld refinements verify the rare-earth substitution while ab initio calculations prove that Ce3+ occupies the Na+ sites. NaMgBO3:Ce3+ is excited by a broad range of near-UV light sources and produces a blue-cyan emission with a high (internal) quantum efficiency, minimal thermal degradation, and zero-chromaticity drift at elevated temperatures. Fabricating a near-UV (lambda(ex) = 370 nm) pumped pc-wLED using NaMgBO3:Ce3+ along with commercially available phosphors demonstrates a well-distributed warm white light with a high color-rendering index (R-a) of 91 and a low correlated color temperature (CCT) of 3645 K. Closing the cyan cavity with NaMgBO3:Ce3+ is ideal for generating a pleasant, full-spectrum warm white light.
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