4.2 Article

Investigations on selectivity of gas-liquid reactions in capillaries

Journal

CHEMIE INGENIEUR TECHNIK
Volume 92, Issue 5, Pages 624-628

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cite.201900144

Keywords

Coiled flow inverter; Gas-liquid reaction; Michaelis-Menten kinetic; Taylor flow

Funding

  1. German Research Foundation (DFG) [KO2349/13-1]

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Biocatalysis offers a broad spectrum of possible ecological and economic advantages over conventional chemical catalysis processes, e.g., lower energy consumption and high enantio selectivity. The focus of this work is on gas-liquid reactions. These are of great importance in the chemical and biochemical industry and subject of current research since they are often limited by mass transfer or show low selectivity. Different suitable biocatalytically gas-liquid reaction systems were tested in capillary reactor designs in order to obtain information about the interaction between reaction and fluid mechanics. Furthermore, an optical measuring method was established. The experiments were performed in batch mode in a glass beaker with a flow cuvette for UV/Vis measurement of product concentration.

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