Journal
CHEMICAL REVIEWS
Volume 120, Issue 16, Pages 8267-8302Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.9b00575
Keywords
-
Categories
Funding
- Army Research Office, Department of Army Material command [W911NF-16-2-0106]
- Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-08ER46519]
- National Science Foundation, Division of Materials Research [DMR-1506059]
- National Science Foundation, Division of Chemistry [CHE-1661655]
- United States Department of Education GAANN Fellowship [P200A150251]
- Department of Defense (DoD) through the National Defense Science and Engineering Graduate (NDSEG) Fellowship Program
- Achievement Rewards for College Scientists (ARCS) Foundation Fellowship
- USD/R&E (The Under Secretary of Defense-Research and Engineering), National Defense Education Program (NDEP)/BA-1, Basic Research in the Science Mathematics and Research for Transformation (SMART) Scholarship Program
- Asahi Kasei Corporation
Ask authors/readers for more resources
Metal-organic frameworks (MOFs) are inherently crystalline, brittle porous solids. Conversely, polymers are flexible, malleable, and processable solids that are used for a broad range of commonly used technologies. The stark differences between the nature of MOFs and polymers has motivated efforts to hybridize crystalline MOFs and flexible polymers to produce composites that retain the desired properties of these disparate materials. Importantly, studies have shown that MOFs can be used to influence polymer structure, and polymers can be used to modulate MOF growth and characteristics. In this Review, we highlight the development and recent advances in the synthesis of MOF-polymer mixed-matrix membranes (MMMs) and applications of these MMMs in gas and liquid separations and purifications, including aqueous applications such as dye removal, toxic heavy metal sequestration, and desalination. Other elegant ways of synthesizing MOF-polymer hybrid materials, such as grafting polymers to and from MOFs, polymerization of polymers within MOFs, using polymers to template MOFs, and the bottom-up synthesis of polyMOFs and polyMOPs are also discussed. This review highlights recent papers in the advancement of MOF-polymer hybrid materials, as well as seminal reports that significantly advanced the field.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available