Tailoring energy release of nano-Si based thermites via incorporation of Ti nanoparticles

This work explores the ignition mechanism of silicon (Si) based thermites, and it is supposed that the phase change of silica (SiO2) coating on the Si core producing fractures may play a crucial role in the ignition of Si-based thermites. Several Si-based thermites were evaluated by the combustion test and calorimeter, and potassium perchlorate (KClO4) is turned out to be a promising oxidizer given the high reactivity and considerable heat release. Titanium (Ti) nanoparticles with a lower onset oxidization temperature than Si were incorporated into Si/KClO4 system via a facile sonicating method. The ignition temperature of Si/KClO4 has reduced markedly by similar to 80-130 degrees C with significant increases of similar to 5-8x in pressurization rate and decreases by a factor of similar to 2-3 in burn time when adding 30-70% Ti by mole into the fuel. The combustion efficiency is improved dramatically from similar to 59% to similar to 73%. The enhanced combustion performance could be attributed to the lower ignition temperature of Ti/KClO4 leading to the initiation reaction of the ternary composites, thus promoting energy release and the reactivity of the ternary system. This work not only investigates the ignition mechanism of Si-based thermites but also sets a stage for tuning the ignition and combustion of Si-based thermites via facile incorporation of Ti nanoparticles.