Kinetics and mechanisms of enhanced degradation of ibuprofen by piezo-catalytic activation of persulfate

This study investigates the degradation of a refractory emerging contaminant (i.e., ibuprofen) by a newly developed piezoelectric catalytic persulfate (PS) activation process. BaTiO3 nanoparticles (NP) and nanowires (NW) were hydrothermally synthesized and used as the piezo-catalysts to activate PS under ultrasonic irradiation for radical generation and ibuprofen (IBP) degradation. IBP was efficiently degraded in the US/BTO NW/PS system with a pseudo first order rate constant of 0.0818 min(-1), and the rate constant was faster than that in the US/BTO NP/PS (0.0492 min(-1)), US/BTO NW (0.0324 min(-1)) and US/PS (0.0057 min(-1)) systems. The outstanding performance of IBP degradation in the US/BTO NW/PS system was attributed to the continuous generation of center dot SO4- and center dot OH via PS activation by the piezo-catalysis induced electrons. center dot SO4- and center dot OH contributed 53% and 44% to the IBP degradation respectively. Meanwhile, center dot O-2, O-1(2) and H2O2 were in-situ formed and identified as key intermediates for the generation of SO4- and center dot OH. The IBP was partially mineralized and transformed to other organic compounds. The degradation products were identified using the UPLC/ESI-tqMS and a degradation pathway was proposed, which involved a sequence of hydroxylation, decarboxylation/demethylation and ring-opening reactions with center dot SO4- and center dot OH. This study demonstrates a new energy-saving approach to activating PS for micropollutant abatement and also provides insights into the mechanisms of the PS activation by the piezoelectric catalysis.