Journal
CATALYSIS COMMUNICATIONS
Volume 133, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2019.105828
Keywords
Se-catalysis; Selenium; Oxidation; Iron; C = C scission
Categories
Funding
- Jiangsu Provincial Six Talent Peaks Project [XCL-090]
- Natural Science Foundation of Jiangsu Province [BK20181449]
- Nature Science Foundation of Guangling College [ZKZD17005, ZKZZ18001]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
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Selenium-doped Fe2O3 (Se@Fe2O3) was prepared by treating Fe2O3 with in situ generated NaHSe. The material was a low-cost but highly efficient and recyclable catalyst for oxidative scission of C=C. Compared with reported homogeneous (RSe)(2) catalyst (R = c-C6H11, n-C4H9 etc), the turnover number of Se@Fe2O3 was enhanced (TON = 694 vs. 7) and the reaction did not require excess H2O2, affording a safer and more efficient method for alkene degradation under mild conditions.
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