Journal
CARBON
Volume 157, Issue -, Pages 761-766Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.10.069
Keywords
CVD carbon nanocoils; Ag nanoparticles/nanosheets; Stirring assisted electrodeposition; Glucose sensor
Funding
- National Natural Science Foundation of China [51661145025, 11274055]
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A novel strategy has been adopted to prepare a free-standing three-dimensional (3D) electrode for nonenzymatic glucose electro-oxidation. Carbon nanocoils (CNCs) has been grown on the surface of nickel foam (NF) by catalyst assisted chemical vapors deposition to form a CNC@NF substrate. Subsequently, the 3D substrate has been coated with silver nanoparticles/sheets through electrodeposition under continuous stirring to form a network structure of Ag@CNC@NF electrode. Such a 3D catalyst electrode allows efficient diffusion and consequently boosts the electrocatalytic oxidation of glucose. Therefore, the 3D electrode provides excellent glucose sensing performance in terms of ultra-high sensitivity of 3.64 x 10(10) mu A mM(-1) cm(-2) and quick response time of 0.1s with a detection limit of 6 nM. These features make the sensor potentially practical candidate for application to biosensors. (C) 2019 Elsevier Ltd. All rights reserved.
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