4.4 Article

Aliphatic Oxaboroles Enabling Remarkable Recognition of Diols

Journal

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 93, Issue 4, Pages 576-580

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20200007

Keywords

Oxaborole; Recognition; Sugar

Funding

  1. Kanazawa University SAKIGAKE project 2018
  2. Takeda Science Foundation
  3. [19K21126]

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5-Membered ring aliphatic oxaboroles revealed unique characteristics in their reactivity with diols. The aliphatic oxaborole derivatives exhibited a higher complexation activity for Alizarin Red S than phenyl-, alkylboronic acid, benzoxaborole, and oxaborin. Furthermore, the sugar recognition ability depended on the chirality of the aliphatic boroles.

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