Journal
APPLIED SURFACE SCIENCE
Volume 507, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2019.144972
Keywords
Gold nanorods; Gold nanosphere; Montmorillonite clay; Layer-by-layer thin films; Electrochemical sensors; Metal ions detection
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Funding
- FAPESP [2016/19387-0]
- CNPq [400285/2016-9]
- CAPES
- Ineo network
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We report the effects of different gold nanostructures incorporated into sodium montmorillonite clay mineral (Na+-MMT) through thin films based on electrostatic interactions. The nanocomposite films were fabricated by layer-by-layer (LbL) technique using gold nanosphere (AuNSs) and gold nanorods (AuNRs) as cationic colloidal solutions, interacting with Na+-MMT clay as anionic dispersion. Higher performance was evaluated from electrochemical measurements for the detection of metal ions traces (Cd2+ and Cu2+). The interactions between materials were confirmed by UV-vis and FTIR spectroscopies and the effects of the Au nanostructures shape on Na+-MMT clay structures properties are confirmed by X-ray diffraction patterns. The results demonstrate that the AuNRs increase the lamellar space of Na+-MMT clay, consequently, increasing the roughness and favoring directly electrochemical response, with higher sensitivity and lower limits detection. Recovery was found to be 98.1% for cadmium but as high as 103.1% for copper, indicating that the modified electrode provides excellent reproducibility, stability, and promising applicability in the real water sample.
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