Journal
APPLIED CLAY SCIENCE
Volume 187, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.clay.2020.105495
Keywords
Layered double hydroxides; Chloride adsorption; Anion-exchange; Kinetic; Thermodynamics
Funding
- Natural Science Foundation of China [51478164]
- Natural Science Foundation of Jiangsu Province [BK20181306]
Ask authors/readers for more resources
MgAl layered double hydroxides (MgAl-LDHs) directly intercalated with aminobenzoate ions were synthesized by conventional calcination-rehydration method. The kinetic, thermodynamic and equilibrium studies on the chloride adsorption of the as-fabricated LDHs were performed by batch experiment technique. Besides, the microstructures of as-obtained MgAl-LDHs were observed by X-ray diffraction and FT-IR spectra. The results indicate that the chloride adsorption on the MgAl-LDHs is significantly affected by the initial pH value, LDHs dosage and contact time. Langmuir isotherm can provide a better fit for the experimental data of Cl- adsorption on the MgAl-LDHs than Freundich isotherm. The negative values of Gibbs free energy change (Delta G(0)) and standard enthalpy change (Delta H-0) for the process calculated using Langmuir constants are obtained, confirming the spontaneous and exothermic nature of the chloride adsorption process. In addition, the quasi -second order kinetic model is well suitable to describe the chloride adsorption process. The anion exchange in the interlayer of MgAl-LDHs is contributed to the Cl- adsorption, which has been demonstrated by the microstructure observation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available