Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 27, Pages 10802-10806Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201916492
Keywords
nanocomposites; Perovskite nanoparticles; polymer ligands; polymer zwitterions; time-resolved photoluminescence
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Funding
- National Science Foundation [NSF-CHE 1904660]
- Department of Energy, Office of Basic Energy Sciences [DE-SC0016208]
- Cluster on Nanostructured Materials of the Center for UMass/Industry Research on Polymers (CUMIRP)
- U.S. Department of Energy (DOE) [DE-SC0016208] Funding Source: U.S. Department of Energy (DOE)
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Functional polymers with sulfobetaine or phosphorylcholine zwitterions as pendent groups are demonstrated as both ligands and host matrices for CsPbBr3 perovskite nanoparticles (PNPs). These polymers produce nanocomposite films with excellent NP dispersion, optical transparency, and impressive resistance to NP degradation upon exposure to water. Multidentate interactions of the zwitterion-containing copolymers with the PNPs induce dispersed or weakly aggregated nanocomposite morphologies, depending on the extent of zwitterionic functionality in the polymer. Incorporating additional functionality into the polymers, such as benzophenone pendent groups, yields lithographically patternable films, while time-resolved photoluminescence measurements provide insight into the electronic impact of PNPs in zwitterionic polymer matrices.
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