Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 8, Pages 3073-3077Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912845
Keywords
cadmium; CO2 reduction; electrocatalysis; gold nanoclusters; two-phase anti-galvanic reduction
Categories
Funding
- National Natural Science Foundation of China [21829501, 21925303, 21905284, 21771186, 21706265, 21603234, 21573212, 21573240, 21222301, 21171170, 21528303]
- China Postdoctoral Science Foundation [Y94G4E356B]
- CASHIPS Director's Fund [BJPY2019A02]
- Key Program of 13th five-year plan, CASHIPS [KP-2017-16]
- Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology [2017FXCX002]
- National Key R&D Program of China [2017YFA0207302]
- Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences [MPCS-2019-A-09]
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Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well-defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two-phase anti-galvanic reduction (AGR) method is presented for precisely tailoring Au-44(TBBT)(28) to produce Au47Cd2(TBBT)(31) nanoclusters with a hard-sphere random close-packed structure, exhibiting Faradaic efficiencies of up to 96 % at -0.57 V for the electrocatalytic reduction of CO2 to CO.
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